The carbonates become more thermally stable down the group. If "X" represents any one of the elements: Your IP: 185.35.187.96 Hence, Thermal stability order : $\ce{MgCO3 CaCO3 SrCO3 BaCO3}$ So the correct order of stability of carbonates of Group IIA is B a C O 3 > S r C O 3 > C a C O 3 > M g C O 3 . Completing the CAPTCHA proves you are a human and gives you temporary access to the web property. All the carbonates in this group undergo thermal decomposition to the metal oxide and carbon dioxide gas. The thermal stability; of these carbonates increases down the group, i.e., from Be to Ba, BeCO 3 < MgCO 3 < CaCO 3 < SrCO 3 < BaCO 3 BeCO 3 is unstable to the extent that it is stable only in atmosphere of CO 2. In group 1 and 2, the nitrates and carbonates get more stable down the group. Still have questions? Join Yahoo Answers and get 100 points today. Calcium ion also has a smaller radius and so a higher charge density giving it a greater polarising power allowing it to distort the bonding 3H2O, evaluated by in situ laboratory parallel-beam X-ray powder diffraction: New constraints on CO2 sequestration within minerals, Journal of Hazardous Materials 178, no.1-3 1-3 (Jun 2010): 522–528. * Due to same reason, carbonates of group-1 are more stable than those of group-2. Solution for group 1 elements with that of group 2 on the basis of the following:… The carbonates For example, Group 2 carbonates are virtually insoluble in water. This decreases the charge density and the ability of the cation to polarize the anion. Going down group II, the ionic radii of cations increases. 18. The rest of the Group 1 carbonates do not decompose at laboratory temperatures, although at higher temperatures this becomes possible. The Facts. Performance & security by Cloudflare, Please complete the security check to access. * Thermal stability of group-1 and group-2 carbonates (also of bicarbonates) increases down the group as the polarizing power of the metal ion decreases. This means that the enthalpy change from the carbonate to the oxide becomes more negative so more heat is needed to decompose it. I am a metal and placed above iron in the activity series. For example, alkali metal salts such as sulptlates, carbonates, nitrates and perchlorates possess greater stability than the corresponding salts of less reactive metals, or the corresponding free acids. If you are at an office or shared network, you can ask the network administrator to run a scan across the network looking for misconfigured or infected devices. The thermal stability; of these carbonates increases down the group, i.e., from Be to Ba, BeCO 3 < MgCO 3 < CaCO 3 < SrCO 3 < BaCO 3 BeCO 3 is unstable to the extent that it is stable only in atmosphere of CO 2. It describes and explains how the thermal stability of the compounds changes as you go down the Group. • When metal carbonates are heated, they break down to … All the carbonates in this group undergo thermal decomposition to the metal oxide and carbon dioxide gas. The effect of heat on the Group 2 carbonates. It's how resistant a molecule is to decomposition at higher temperatures. From Li to Cs, due to larger ion size, hydration enthalpy decreases. All the carbonates in this Group undergo thermal decomposition to give the metal oxide and carbon dioxide gas. Carbonate Structure. A simple relationship between the reactivity of the metal and the stability of its compounds, such as the carbonate here, will have to suffice. All these carbonates decompose on heating to give CO 2 and metal oxide. Thermal stability increases down the group because the size of the cation (positive ion) increases, so the lattice energy of the carbonate decreases, but the lattice energy of the oxide decreases faster. What is the  molar concentration of sodium nitrate .? Correct order of stability of group 2a metal carbonates is 1 See answer mohitrathimr4440 is waiting for your help. Which of the following is likely to occur after decreasing the pressure of a liquid. All of these carbonates are white solids, and the oxides that are produced are also white solids. Magnesium carbonate (the most soluble one I have data for) is soluble to the extent of about 0.02 g per 100 g of water at room temperature. Both carbonates and nitrates of Group 2 elements become more thermally stable down the group. Thermal decomposition is the term given to splitting up a compound by heating it. All the carbonates in this Group undergo thermal decomposition to give the metal oxide and carbon dioxide gas. The carbonates of group-2 metals and that of lithium decompose on heating, forming an oxide and carbon dioxide . Carbonates of metal: Thermal stabilityThe carbonates of alkali metals except lithium carbonate are stable to heat. Also, does thermal stability increase or decrease as you go down group 1 (with explanation please)? All the Group 2 carbonates and their resulting oxides exist as white solids. Upon heating, carbonates decompose into oxide and carbon dioxide; The thermal stability of group-1 and group-2 carbonates increase down the group. Also, lithium carbonate is unstable due to the high polarising power of the lithium ion due to its small size (same explanation as for the Group 2 carbonates). Thermal stability of group 2 carbonates experiment Group 1 and 2 metal hydroxides AQA C2 Acids, Bases & Salts Help Chemistry igcse 0620/33 may/june 2011 Are Group 2 oxides soluble in water? All the carbonates in this group undergo thermal decomposition to the metal oxide and carbon dioxide gas. Down the group, the carbonates require more heating to decompose. You may need to download version 2.0 now from the Chrome Web Store. Decomposition becomes more difficult and thermal stability increases. Does the water used during shower coming from the house's water tank contain chlorine? Stability of metal carbonates One common reaction of any metal carbonates is known as thermal decomposition. Thermal stability of Alkaline earth metals carbonates increases down the group. Thermal Stability is the decomposition of a compound on heating. 6. The same occurs in group 1. • From Li to Cs, thermal stability of carbonates increases. I know stability increases as you go down group 2, please explain why in language a good A level student can understand. 1. (substitute Na, K … You will often find unusual properties for the first member of a group. If "X" represents any one of the elements: rihu27 rihu27 Answer: down the group the stability of metellic carbonates imcreass. Add your answer and earn points. The higher the temperature required to decompose something, the more thermally stable it will be. How many grams of glucose would be formed in a reaction in which 23.576 grams of carbon dioxide were consumed? The quote from your text: So the stability that you are referring to is thermal stability.This is an important detail. The term "thermal decomposition" describes splitting up a compound by heating it. Explanation: New questions in Chemistry. I cannot wrap my head around this. Thermal Stability. 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